a) \(n_{CH_4}=\dfrac{V_{\left(\text{đ}ktc\right)}}{22,4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)

b) Theo PTHH: \(n_{H_2O}=n_{O_2}=2n_{CH_4}=2.0,4=0,8\left(mol\right)\)

\(m_{H_2O}=n.M=0,8.18=14,4\left(g\right)\)

c) \(V_{O_2\left(\text{đ}ktc\right)}=n.22,4=0,8.22,4=17,92\left(l\right)\)

  D. 42,67 lít 

D

D

a, Ta có: \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_C\)

\(n_{H_2O}=\dfrac{10,8}{18}=0,6\left(mol\right)\Rightarrow n_H=0,6.2=1,2\left(mol\right)\)

m = m_C + m_H = 0,4.12 + 1,2.1 = 6 (g)

b, Theo ĐLBT KL, có: m + m_O2 = m_CO2 + m_H2O

⇒ m_O2 = 22,4 (g) \(\Rightarrow n_{O_2}=\dfrac{22,4}{32}=0,7\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,7.22,4=15,68\left(g\right)\)

\(\Rightarrow V_{kk}=\dfrac{15,68}{20\%}=78,4\left(g\right)\)

a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)

b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)

c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)

\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)

Tính % thể tích các khí :

% V C 2 H 2  = 0,448/0,896 x 100% = 50%

% V CH 4  = % V C 2 H 6  = 25%

\(a,n_{hh\left(CH_4,C_2H_4,C_2H_2\right)}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ n_{hh\left(C_2H_4,C_2H_2\right)}=0,4-0,1=0,3\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}a+b=0,3\\28a+26b=8,1\end{matrix}\right.\Leftrightarrow a=b=0,15\left(mol\right)\)

PTHH:

\(CH\equiv CH+2Br-Br\rightarrow CHBr_2-CHBr_2\)

\(CH_2=CH_2+Br-Br\rightarrow CH_2Br-CH_2Br\)

\(b,\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,4}.100\%=25\%\\\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,15}{0,4}.100\%=37,5\%\end{matrix}\right.\)

c, PTHH:

\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+H_2O\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3\downarrow+H_2O\\ \rightarrow n_{BaCO_3}=n_{CO_2}=0,1+0,15.0,15.2=0,7\left(mol\right)\\ m_{BaCO_3}=0,7.197=137,9\left(g\right)\)

Đáp án D

• hhX gồm n_{CnH2n + 2} = 1,68 : 22,4 = 0,075 mol; 

Đốt cháy 0,075 mol C_nH_{2n + 2}; 0,05 mol C_mH_2m+2–2a → 0,225 mol CO₂

Số C trung bình = 0,225 : 0,125 ≈ 1,8 → Ankan là CH₄.

Ta có: n_CO2 = 0,075 + 0,05m = 0,225 → m = 3

Nhận thấy n_Br2 pứ = 2n_CmH2m+2–2a ⇒ C_xH_y còn lại có a = 2 Û C_mH_2m–2

Û C₃H₄

VCH4 = 2,24 (l)

VC2H4 = 8,96 - 2,24 = 6,72 (l)

nC2H4 = 6,72/22,4 = 0,3 (mol)

PTHH: C2H4 + Br2 -> C2H4Br2 

Mol: 0,3 ---> 0,3

mBr2 = 0,3 . 160 = 48 (g)

\(a,PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\\ m_{Al_2O_3}=n.M=0,2.102=20,4\left(g\right)\)

\(b,n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ Lập.tỉ.lệ:\dfrac{n_{Al}}{4}>\dfrac{n_{O_2}}{3}\Rightarrow Al.dư\\ Theo.PTHH:n_{Al\left(pư\right)}=\dfrac{4}{3}.n_{O_2}=\dfrac{4}{3}.0,2\left(mol\right)\\ n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(pư\right)}=0,4-0,2=0,2\left(mol\right)\\ Theo.PTHH:n_{Al_2O_3}=\dfrac{1}{2}.n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{Al_2O_3}=n.M=0,1=102=10,2\left(g\right)\)